Measurement of the gas temperature in plasmas in and in contact with liquids
نویسندگان
چکیده
The use of optical emission spectroscopy and specifically the OH(A-X) rotational distribution is investigated to obtain gas temperatures in plasmas in and in contact with liquids. The rotational distribution of OH(A-X) is often non-Boltzmann and only the rotational lines with the smallest rotational numbers are in equilibrium with the gas temperature. The possible reasons of this non-equilibrium are discussed in detail in this contribution. The rotational temperature of N2(C-B) by introducing trace impurities of N2 in the discharge is a good alternative to obtain an independent gas temperature measurement from the rotational temperature obtained by OH(A-X).
منابع مشابه
Modeling Solubility Behavior of CO2 in [C2-mim][BF4] and [C4-mim][BF4] Ionic Liquids by sPC-SAFT Equation of State
The simplified perturbed chain statistical associating fluid theory (sPC-SAFT) Equation of State (EOS) was proposed to describe the thermodynamic properties of pure ionic liquids (ILs). A set of sPC-SAFT parameters for 2 ILs was obtained by fitting the experimental liquid densities data over a wide range of temperature at atmospheric pressure. Good agreement with experimental density data was o...
متن کاملبررسی ارتباط میان انتشار دی اکسید گوگرد و میست اسید سولفوریک با میزان مواجهه فردی کارکنان یکی از واحدهای مجتمع پتروشیمی
Background and Aim The oxides of sulphur are among those chemical substances that are increasingly used and their consumption is even growing in different places everyday. Sulphuroxides are used in chemical industries, paper manufacturing, printing rollers, recovering burned (consumed) coal, supplying and producing sulphuric acid, and in bleaching liquids. Determination and evaluation of th...
متن کاملInvestigation of Thermodynamic Consistency Test of Carbon Dioxide (CO2) in Room-Temperature Ionic liquids using Generic van der Waals Equation of State
Thermodynamic consistency test of isothermal vapor-liquid equilibrium (VLE) data of various binary systems containing Carbon dioxide (CO2)/Room temperature ionic liquids (RTILs) have been investigated in wide ranges of pressures in each isotherm precisely. In this paper Generic van der Waals (GvdW) equation of state (EoS) coupled with modified van der Waals Berthelot mixing rule has ...
متن کاملModeling the Solubility of Acid Gases in Ionic Liquids
In this work, the PC-SAFT equation of state (EoS) has been used to model the solubility of acid gases (CO2 and H2S) in two imidazolium-based ionic liquids (ILs) ([C8-mim][PF6] and [C8-mim][Tf2N]). Parameters of pure ILs were estimated using experimental densities. Two strategies were considered to model densities of pure ILs. In strategy 1, ILs were modeled as nonassociating compounds and in st...
متن کاملDetection and Determination of some Migrated Chemicals from Plastic Containers into Different Drinks and Liquids Using Dispersive Liquid-liquid Microextraction Prior to Gas Chromatography
Migration of chemicals from plastic containers into drinks and liquids containing them, is supposed to be a hazardous phenomenon and results in many health problems. Sample preparation is of great importance due to trace amounts analysis of these compounds. In this research, dispersive liquid–liquid microextraction is applied for the extraction and preconcentration of the migrated compounds pri...
متن کامل